Twilight‘s leading lady glittered in a metallic Guishem cocktail dress with yellow and black accents.
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Charlize Theron
"You have to just not try to be trendy and do what's comfortable," the Lanvin-clad new mom (sporting Cartier jewels) told MTV's Kat Graham. "At the end of the day, I have to put it on and look like me."
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Julianne Hough
Rock of Ages' Hough showed a bit of skin in Sally LaPointe's long sleeve black mini dress, which she accessorized with Jimmy Choo shoes and a Kelly Wearstler clutch and earrings.
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Lucy Hale
Pretty Little Liars' Hale stunned in Catherine Malandrino's color-blocked silk halter dress featuring a coral bodice, teal skirt and cobalt sash. Hale finished her look with Edie Parker's silver confetti clutch.
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Elizabeth Banks
The Hunger Games actress opted for a black stretch crepe long sleeve Elie Saab jumpsuit with lace cutout panels. She finished off her look with black Ruthie Davis heels.
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Nikki Reed
The Twilight star -- who attended Sunday's show with her husband Paul McDonald -- glittered in Randi Rahm's cap sleeved gold beaded cocktail dress.
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Shailene Woodley
"I feel awesome and comfortable. It's a little out there and I love it!" The Descendants star told MTV of her head-to-toe Stella McCartney look.
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Janelle Monae
The "Tightrope" singer went for a menswear-inspired look, complete with a black hat and loafers.
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Kat Graham
The Vampire Diaries star wowed in Maria Lucia Hohan when serving as a red carpet fashion correspondent for MTV.
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Victoria Justice
The Nickelodeon star hit the red carpet in an asymmetrical white and yellow Erin Fetherston dress accessorized with a black belt and clutch.
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Paris Hilton
Hilton turned heads in a sleeveless black cocktail dress with beaded accents.
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Ellie Kemper
The actress was all smiles in a yellow floral print Dolce & Gabbana dress, which she accessorized with Dorozio jewelry and Alexander McQueen shoes.
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Holland Roden
Teen Wolf's leading lady rocked an embroidered red Mandalay caps sleeve cocktail dress.
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Eva Amurri Martino
Susan Sarandon's newlywed daughter attended Sunday's show wearing Holmes & Yang's petal sleeve dress.
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Louise Roe
TV personality Roe selected David Meister's purple metallic knit asymmetrical off the shoulder evening gown.
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Christina Ricci
The actress wore a custom dress designed by Christian Siriano.
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Leighton Meester
Gossip Girl's star wore a Christian Cota design accessorized with Brian Atwood heels, Neil Lane jewels and a Jimmy Choo bag.
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Emma Watson
Perks of Being a Wallflower's Watson turned heads in colorful design by Brood and Tabitha Simmons shoes.
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Ciara
The singer was ravishing in a red Balmain dress and Christian Louboutin shoes.
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Emma Stone
The Spider-Man actress dressed up her black and tan ensemble with Brian Atwood pumps.
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Jessica Biel
Justin Timberlake's fiancee flaunted her engagement ring -- and showed off her curves in a long sleeve white Chanel ensemble -- at Sunday's show.
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Nicky Hilton
The heiress chose a black strapless dress and black pumps.
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Jenna Dewan
Channing Tatum's wife looked summery chic in a plunging seafoam green and white LUBLU cocktail dress.
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Mila Kunis
The Blood Ties actress showed off her sexy stems in a colorful Fendi mini dress paired with black pumps.
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Amber Rose
Wiz Kalifa's fiancee wore a mint green mini dress to Sunday's show.
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Kate Beckinsale
The actress sported a pumped-up ponytail and a nude turtleneck Dior mini.
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