Gossip Girl: What They Wore Last Night

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Season 5: Episode 20

Lola Rhodes looked like she fit right in with the Upper East Side in this Philosophy di Alberta Ferretti metallic crochet knit dress and her Nancy Gonzalez Shoulder Bag.

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Season 5: Episode 20

Diana Payne flaunted her most eye-catching assets in this Alexander McQueen shirt dress' cowl neck. She paired her look with nude Fendi Bow Platform Pumps.

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Season 5: Episode 18

Serena van der Woodsen sported a plain black dress by Porter Grey and a necklace by MCL.

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Season 5: Episode 18

Ivy Dickens hosted her first Upper East Side soiree in a gold Vera Wang dress paired with black slingback pumps by Zara and earrings by Sequin.

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Season 5: Episode 18

Lily Van der Woodsen accessorized her black Christian Dior dress with a Badgley Mischka statement necklace and a Christian Dior bag.

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Season 5: Episode 15

Blair wore a gorgeous scarlet Reem Acra Resort 2012 Silk Gown paired with a VBH Manila Sparkle clutch.

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Season 5: Episode 15

Blaire wore a red wool-blend coat by Valentino.

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Season 5: Episode 13

Blair donned a strapless A-line Vera Wang gown with a fitted bodice when she finally tied the knot with Prince Louis Grimaldi.

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Season 5: Episode 13

As Blair's maid of honor, Serena wore Vera Wang's "Farrah" gown, a long organza and metallic tulle gown with a corset bodice and blossom flange skirt, straight from the designer's spring 2011 wedding collection. The bridesmaids were decked out in short, one-shoulder organza dressed with a bias-cut flange skirt from Wang's line for David's Bridal, White by Vera Wang.

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Season 5: Episode 13

During a dream montage where she portrayed the late Marilyn Monroe, Serena looked red hot in a Redux Charles Chang-Lima One-Shoulder Mermaid Gown.

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Season 5: Episode 12

Blair looked pretty in a robin's egg blue Diane von Furstenberg Milford Alpaca Coat over a Carolina Herrera organza dress teamed with Stuart Weitzman platform pumps.

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Season 5: Episode 12

Serena put together quite the ensemble with a red and black Marc by Marc Jacobs sweater, an embellished mini by Haute Hippie worn over grey leggings and a Vena Cava coat. She accessorized with a Valentino Demetra leather satchel and Rachel Roy boots.

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Season 5: Episode 11

Blair is dressed to the nines in an Alice + Olivia Oshi Boucle skirt and a Cryphon Sherlock Cape paired with Fendi’s yellow Peek-a-Boo tote and maroon Miu Miu Platform Loafer pumps.

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Season 5: Episode 11

Serena sparkles in a Lorena Sarbu Scallop Dress paired with pewter leggings.

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Season 5: Episode 11

Blair is a winter white sight in a Diane von Furstenberg Mikhaila Wool Coat.

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Season 5: Episode 10

Fringe benefits! Serena sparkled in an strapless ombre mini by Marchesa and Martine Wester emerald drop earrings.

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Season 5: Episode 10

Blair got dressed in a red printed Balenciaga “Indienne” frock worn underneath a mustard-colored jacket by Diane von Furstenberg.

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Season 5: Episode 10

Charlie shined in Badgley Mischka from head to toe, clad in the designer’s beaded cowl-neck gown and tiered earrings.

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Season 5: Episode 9

Charlie sported a striped Marc by Marc Jacobs 'Camino' Sweater, which she accessorized with a Susanna Galanis Necklace.

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Season 5: Episode 9

Scarlet fever! Blair wore a Donna Karan trapeze sweater paired with black leggings and Yves Saint Laurent Tribtoo Cap-Toe Pumps.

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Season 5: Episode 9

Serena channeled Foxy Cleopatra in a gold Diane von Furstenberg halter floor-length 'Clarice' gown.

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Season 5: Episode 8

In a coral Alberta Ferretti Embellished Neck Tie Chiffon Dress, Moschino Ruffle Pearl Tweed Jacket, a Marc Jacobs quilted handbag and Roger Vivier platform heels.

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Season 5: Episode 8

Serena got gussied up in a chic black L'Agence Layered Dress, which she paired with Dolce & Gabanna pumps.

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Season 5: Episode 8

Blair dazzled in a Christian Dior Embellished Bow Dress.

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Season 5: Episode 8

The leggy blonde rocked a Mary Katrantzou Spring/Summer 2011 Print dress with a high-low hemline and Christian Louboutin Winter Trash Slingbacks.

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Season 5: Episode 7

Blair channeled her animal instinct in a Dolce & Gabbana Leopard Print Chemise Dress. She accessorized with a Roger Vivier Diligence Satchel and cuff, plus 3.1 Phillip Lim Black Multi Calder T-strap Pumps.

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Season 5: Episode 7

Serena rocked a Moschino Spring 2010 RTW Black Beaded Cowl Neck Dress.

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Season 5: Episode 7

Serena showed off her gorgeous gams in a Rodarte skirt paired with an Haute Hippie Feather Sequin Vest and Brian Atwood Power Studs Suede Platform Pumps. She accessorized with a Mulberry ostrich tote and a Siman Tu necklace.

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Season 5: Episode 7

Ivy donned a Lorena Sarbu Resort 2012 Sequin Embellished Dress.

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Season 5: Episode 6

Charlie rocked a Gryphon dress accessorized with a Swarovski necklace, a Rich Rocks ring and a Sequin bracelet while Nate wore an Armani suit and a button-up shirt by Theory.

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Season 5: Episode 6

Blair donned an orange embroidered Blumarine dress, oxblood Sergio Rossi heels and a sparkling gold bangle by Sequin.

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Season 5: Episode 6

Diana looked devilish in a red-hot Roberto Cavalli dress, nude Jimmy Choo peep toe pumps and earrings by Noir.