Golden Globes 2012: Best Hair and Makeup Looks

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Angelina Jolie

Instead of her usual nude lip color, the star surprised fans with a stunning crimson shade, which matched the red detailing in her dress. Bonus points for her glamorous swept-back bun.

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Charlize Theron

To accent the star's dazzling Cartier diamond headband, hairstylist Enzo Angileri gave her an undone undo. He applied Moroccanoil Frizz Control and let her hair air-dry before curling it with a 2-inch iron and creating a loose side bun.

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Emma Stone

The only thing more stunning than the star's plum Lanvin dress? Her intense metallic smoky eye look courtesy of celebrity makeup artist Rachel Goodwin, who used a mix of pewter and gunmetal shadows and Chanel Intense Eye Pencil in Noir.

To create her edgy updo, stylist Mara Roszak twisted pieces into a loose, messy updo and secured with a Lanvin hair accessory and Biolage Freeze Fix Hair Spray.

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Evan Rachel Wood

To accent the star's show-stopping Gucci gown, hairstylist Marcus Francis created a classic, yet modern look using Phyto Volume Actif for lift in the front and a 3/4-inch curling iron for some texture and bend at the ends.

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Jessica Biel

"We wanted Jessica's hair to compliment the 'bohemian luxury' feel of her dress," says celebrity stylist Davy Newkirk who gave the star's mane a boost with Alterna Bamboo Volume Weightless Whipped Mousse before creating loose waves with texturizing spray and a large curling iron.

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Kristen Wiig

"I wanted Kristen's hair to be cool and modern, so we kept her hair down and created loose waves with lots of texture," says celebrity stylist Mark Townsend. He applied Dove Style+Care Nourishing Amplifier Mousse (available in March) for volume before blow-drying, then wrapped 3-inch sections of hair around a large curling iron.

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Lea Michele

"Lea's Marchesa gown inspired me to create a romantic and sexy French twist with lots of texture," says celebrity stylist Mark Townsend, who curled the star's hair before gathering it into an undo. Cool trick: "I spray my hair pins with Dove Refresh+Care Invigorating Dry Shampoo (available in March) before placing them in the hair to keep them from slipping."

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Mila Kunis

"I was inspired by the dress to create a fresh, sophisticated look with a lot of sex appeal." says makeup artist Tracey Levy, who used a mix of Dior Bronze Original Tan and Diorblush in Passion Fruit to give the star a gorgeous glow.

Hair stylist Mara Roszak gave Kunis a glam, side-parted braided bun using L'Oreal Paris EverStyle Smooth & Shine Serum and L'Oreal Paris Elnett Satin Extra Strong Hold Hairspray to keep the look sleek.

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Natalie Portman

"I wanted to emphasize [her] eyes," says celebrity makeup artist Eileen Kastner-Delag for Dior. After blending several shades of purple shadow on the star's lids, she defined them with Dior Waterproof Eyeliner in Captivating Blue and applied Diorshow Mascara in Black.

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Shailene Woodley

To create the star's elegant undo, celebrity hairstylist Campbell McAuley for Wella Professionals pulled her hair into a low, loose ponytail before twisting into a large bun. He finished the look with Wella Professionals Stay Essential Hairspray.

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Sofia Vergara

"This look is all about the lips. We chose a bright plum lip and kept the eyes soft with bronze shadow and multiple coats of mascara." says celebrity makeup artist Kayleen McAdams, who used CoverGirl LipPerfection Lipcolor in Everlasting followed by CoverGirl LipPerfection Lipliner in Beloved.